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Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study

journal contribution
posted on 2024-11-02, 01:03 authored by Alice O'Connor, Nedaossadat Mirzadeh, Suresh BhargavaSuresh Bhargava, Timothy Easun, Martin Schröder, Alexander Blake
High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

History

Related Materials

  1. 1.
    DOI - Is published in 10.1039/C6CC00923A
  2. 2.
    ISSN - Is published in 13597345

Journal

Chemical Communications

Volume

52

Issue

41

Start page

6769

End page

6772

Total pages

4

Publisher

Royal Society of Chemistry

Place published

United Kingdom

Language

English

Copyright

©The Royal Society of Chemistry 2016 Creative Commons Attribution 3.0 Unported Licence

Former Identifier

2006061519

Esploro creation date

2020-06-22

Fedora creation date

2016-05-12

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    Licence

    CC BY 4.0

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