We describe an easy way to form micro spiral structures resulting from buckling instabilities of an electro jet of a nanoscale polymer fiber of polyvinglpyrrolidone-Cu(NO3)2 (PVP-Cu(NO3)2) sol) and discuss the formation process. We control the morphologies of the fibers into spiral fibers, and free-standing hollow cylinders by connecting an opposite high voltage supply (-5 to -10 kV) on the collector. The microstructured surfaces were observed by scanning electron microscope (SEM). SEM analysis revealed the presence of spirals with diameters of approximately 20 to 30 µm. The structures formed by the nanofibers could be used in diverse fields of nanotechnology, such as micro planar inductor and nanochannels.