Melt-induced fluorescent signature in a simple naphthalenediimide

Bell, Toby; Bhosale, Sheshanath; Forsyth, Craig; Hayne, David; Ghiggino, Kenneth; Hutchison, James; Jani, Chintan; Langford, Steven; Lee, Marcia; Woodward, Clint

Melt-induced fluorescent signature in a simple naphthalenediimide

journal contribution

posted on 2024-11-01, 12:19 authored by Toby Bell, Sheshanath Bhosale, Craig Forsyth, David Hayne, Kenneth Ghiggino, James Hutchison, Chintan Jani, Steven Langford, Marcia Lee, Clint Woodward

The synthesis and fluorescence properties of a naphthalenediimide ditosylate are presented. The fluorescence is highly solvent and morphology dependent with a dramatic change in fluorescence output occurring following melting from a crystalline form. This observation is attributed to thermal disruption of the crystal structure allowing the formation of emissive dimers within the amorphous melt.

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1.
DOI - Is published in 10.1039/c0cc00865f
2.
ISSN - Is published in 13597345

Journal

Chemical Communications

Volume

46

Issue

27

Start page

4881

End page

4883

Total pages

3

Publisher

Royal Society of Chemistry

Place published

United Kingdom

Language

English

Copyright

Former Identifier

2006035109

Esploro creation date

2020-06-22

Fedora creation date

2012-09-21

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Melt-induced fluorescent signature in a simple naphthalenediimide

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