In this paper, an attempt has been made to optimise the sintering process parameters of Al-Si (12%) alloy/fly ash composite using grey relational analysis. Al-Si alloy/fly ash composite was produced using powder metallurgy technique. Al-Si alloy powder was homogenously mixed with various weight percentages of fly ash (5-15 wt.%) and compacted at a pressure ranging from 307 to 512 MPa. The green compacts were sintered at temperatures between 575 and 625°C. Experiments have been performed under different conditions of temperature, fly ash content, and compacting pressure. Taguchi's L9 orthogonal array was used to investigate the sintering process parameters. Optimal levels of parameters were identified using grey relational analysis, and significant parameter was determined by analysis of variance. Experimental results indicate that multi-response characteristics such as density and hardness can be improved effectively through grey relational analysis.