Natural Amphiphilic Shellac Nanoparticle-Stabilized Novel Pickering Emulsions with Droplets and Bi-continuous Structures

Shellac is a natural amphiphilic substance, and its nanoparticles can be used to stabilize Pickering emulsions with droplets and bi-continuous structures. In this study, shellac nanoparticles (SNPs) were produced through the anti-solvent method, and these SNPs were used to produce a series of Pickering emulsions. Fourier transform infrared results showed that SNPs were generated through hydrogen bonding and hydrophobic effects. The contact angle of SNPs was 122.3°, indicating that hydrophobicity was their dominant characteristic. According to the results of confocal laser scanning microscopy, the Pickering emulsions stabilized by SNPs showed oil-in-water, bi-continuous structure, and water-in-oil characteristics, which were dependent on the oil-phase content. The resistance value of the emulsified part of these Pickering emulsion systems significantly increased at an oil-phase ratio of 80-90% (more than 105 Mω), as compared with the 10-70% oil-phase content (around 1 Mω). The viscosity of SNP-stabilized Pickering emulsions with bi-continuous structures was highest at 40% oil-phase content. The porous material prepared by using Pickering emulsions with bi-continuous structures as a template had an interconnected structure and was able to absorb both water and oil. This study indicated that these amphiphilic SNPs readily form bi-continuous structures and effectively stabilize Pickering emulsions with droplets. These SNPs are expected to have increased application in food and pharmaceutical industries.