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Total synthesis of catenioblin B

journal contribution
posted on 2024-11-01, 17:10 authored by Srinivas Theegala, Helmut Hugel, Palakodety Radha Krishna
Herein we report the first total synthesis of catenioblin B (1) via a titanium(IV) mediated regioselective epoxide ring-opening, Grignard reaction, Luche's reduction and TEMPO/BAIB mediated intramolecular cyclization as the key steps.

History

Related Materials

  1. 1.
    DOI - Is published in 10.1016/j.tetlet.2014.09.034
  2. 2.
    ISSN - Is published in 00404039

Journal

Tetrahedron Letters

Volume

55

Issue

43

Start page

5952

End page

5954

Total pages

3

Publisher

Pergamon Press

Place published

United Kingdom

Language

English

Copyright

© 2014 Elsevier Ltd. All rights reserved.

Former Identifier

2006049866

Esploro creation date

2020-06-22

Fedora creation date

2015-01-22

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    Categories

    Keywords

    CatenioblinsGrignard reactionPyranone derivativeRegioselective epoxide ring-openingSharpless epoxidation

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    All rights reserved

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