Unprecedented near-infrared (NIR) emission in diplatinum(III) (d(7)-d(7)) complexes at room temperature
journal contribution
posted on 2024-11-01, 07:24 authored by Martin Bennett, Suresh BhargavaSuresh Bhargava, Eddie Chung-Chin Cheng, Wai Han Lam, Terence Kwok-Ming Lee, Steven Priver, Jorg Wagler, Anthony Willis, Vivian YAMThe synthesis and single-crystal X-ray structures of the first family of efficient NIR emitters with tunable emission energy based on dihalodiplatinum(III) (5d7-5d7) complexes of general formulae [Pt2(µ- C6H3-5-R-2-AsPh2)4X2] (R) Me or CHMe2; X ) Cl, Br or I), together with that of their diplatinum(II) (5d8-5d8) precursors ([Pt2(µ-C6H3-5-R-2-AsPh2)4]) and cyano counterparts (X ) CN), are reported.
